2013年8月30日星期五

Tungsten Ore Recycling

Tungsten Ore Recycling is an important factor in the world’s tungsten ore supply. It is estimated that today some 30% is recycled, and the tungsten ore processing industry is able to treat almost every kind of tungsten-containing scrap and waste to recover tungsten ore and, if present, other valuable constituents.

Contaminated cemented carbide scrap, turnings, grindings and powder scrap are oxidized and chemically processed to APT in a way similar to that used for the processing of tungsten ores. If present, cobalt, tantalum and niobium are recovered in separate processing lines. Other tungsten ore containing scrap and residues might require a modified process.

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Tungsten Ore Selection Equipment

To exploitungsteng tungsten ore, you need first to get tungsten ore focus through the uncooked ore. In tungsten ore concentrator, you need some crushing equipment (breakers), ball mills, feeders, screens and conveyors for the entire plant operatungsteng.

We has gotten devoted to researching and production tungsten ore crushers and mills for almost 30 many years. We’ve quite a little of superb customers around the world. The tungsten ore crushers may be chosen from jaw crusher ( also with far more advanced JC sequence European Jaw Crusher), regular type cone crusher and short hand type cone crusher, influence crusher and new invented vertical shaft effect crusher, and so on. The grinding devices also contain Raymond mill, higher stress suspension grinding mill, new fashion MTW series European Trapezium Grinding Mill and Huge scale LM series Vertical Roller Mill aside from widespread ball mills.

You can find both stationary tungsten ore processing plant and cell crushing screening plant to your convenience. Also, you can purchase connected spare components from our company. BinQ has grown from strength to energy more than the last 30 years, contungstenuously generatungsteng file earnings and work-in-hand. We aim at pursuing best of degree brand together with you. An essential portion of attaining these objectives would be to turn out to be employer of selection for our people as well as the companion of selection to our clients.

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Tungsten Ore Dressing

Tungsten ore dressing methods are mainly hand-selected, HM election, re-election, flotation, magnetic separation and electrostatic separation. Wolframite in order to re-election dominated while scheelite flotation mainly associated. To the full recovery of useful components, improving the quality and tungsten concentrates recycling rate, currently the trend of dressing and smelting technology combined to increase the baking and Leaching and other hydrometallurgical refining methods.
Many types of tungsten ore in earth, there are mainly two; black tungsten ore (wolframite) and scheelite (calcium tungsten ore). There is a variety of ore mineral paragenesis, in order to pass the quality of mineral concentrate to meet the requirement and the associated recovery of useful mineral, generally based on the major component of the ore, taking into account the characteristic of associated component, selection process consisting of two or more method.
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Tungsten Ore Deposits

Most of the tungsten ore deposits are also spatially related to Yenshanian granites. These granites include several intrusions, isotopically dated at 160–180 m. y. and 70–100 m. y. The concentration of trace elements, especially W Mo, Sn, Ta, Nb, Li, and F are relatively high in the granites. In the granites of South China, the average WO3 is 4.35 ppm, but in Yenshanian granites, which are the youngest of these, the average WO3 is 5.16 ppm. In the youngest of Yenshanian granites, a light mica-albite granite has been identified, whose average WO3 is as high as 242.3 ppm. From this line of evidence, the tungsten ore deposits in South China are considered to be genetically related to Yenshanian granites.
Wolframite-sulfide-quartz veins and scheelite skarns provide the bulk of the reserves and production. There are many different kinds of alteration associated with the different tungsten ore deposits, but the principal ones are silicification, greisenization, potash-feldspathization and chloritization.
 
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Tungsten Ore Application

After by the beneficiation process of tungsten, tungsten was silver, high hardness, high melting point, room temperature, from air attack; can be used to manufacture filament and high-speed cutting steel, hard tooling, but also for optical instruments, chemical instrumentation. Tungsten because of its high temperature can maintain most of the high hardness and wear resistance is also used in the production of special steel. WC-based cemented carbide can be used for both cutting tools,mining machinees, and drawing modules. Contact material and the high proportion of alloy used in the manufacture of the gyroscope rotor, aircraft, control the rudder balance weight, radioactive isotopes and radiation shielding material basket, electric vacuum lighting materials. Tungsten and tungsten compounds are widely used in metallurgical materials tungsten raw materials.
Tungsten ore in particular extensive use of many and can produce and refine a variety of different products. For example, pure tungsten, tungsten alloy,tungsten heavy alloy, tungsten carbide, tungsten copper, tungsten powder, tungsten carbide powder, silicon carbide, tungsten electrode. If you want to buy more than one product, you can contact us, we will wholeheartedly for you.

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2013年8月29日星期四

Types of Tungsten Ore Deposits in South of China

And there are 10 types of tungsten ore deposits in South China: granite, porphyry, volcanic, pegmatite, skarn, greisen, wolframite-quartz ± microcline veins, stratabound, ferberite-quartz veins and placer. Most are chronologically related to Yenshanian granites. Integrated field, mineralogic, fluid inclusion and geochemical studies were undertaken to determine the characteristics and origin of the ores.
Most of the tungsten ore deposits are also spatially related to Yenshanian granites. These granites include several intrusions, isotopically dated at 160–180 m. y. and 70–100 m. y. The concentration of trace elements, especially W Mo, Sn, Ta, Nb, Li, and F are relatively high in the granites. In the granites of South China, the average WO3 is 4.35 ppm, but in Yenshanian granites, which are the youngest of these, the average WO3 is 5.16 ppm. In the youngest of Yenshanian granites, a light mica-albite granite has been identified, whose average WO3 is as high as 242.3 ppm. From this line of evidence, the tungsten ore deposits in South China are considered to be genetically related to Yenshanian granites.

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Tungsten Ore Definition from Wekipedia

Tungsten ore is a rock from which the element tungsten can be economically extracted. The ore minerals of tungsten include wolframite, scheelite, and ferberite.Tungsten is used for making many alloys.
Tungsten ore deposits are predominantly magmatic or hydrothermal in origin and are associated with felsic igneous intrusions.

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2013年8月19日星期一

Ferro-Tungsten & Melting Base

Ferro-Tungsten

Ferro-tungsten is a master alloy for the production of tungsten-containing steels.  The raw materials for ferro-tungsten production are rich ore or ore concentrates of wolframite or scheelite.  Also artificial scheelite or soft scrap can be used.  The tungsten trioxide in these compounds can be reduced either carbothermically in electric arc furnaces or metallothermically by silicon and/or aluminum.  Also a mixed carbothermic-silicothermic production is in use.
Commercial ferro-tungsten contains between 75 and 85% W.  It has a steel grey appearance and a fine-grained structure consisting of FeW and Fe2W.  It is supplied in 80–100 mm lumps.

Melting Base

Melting Base is another master alloy in tungsten steel production. It can have various compositions according to the tungsten scrap material in use. The tungsten content varies depending on type between 10 and 38% besides iron and sometimes 5.5% Mo and also 5 to 10% Co.
Different types of scrap materials are mixed to meet the required composition. Reductive melting is done in electric arc furnaces and the melt is finally granulated by casting on a rotating disc and quenching in water (size <10 mm).  

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2013年8月18日星期日

Use of Wolframite

Wolframite was highly valued as the main source of the metal tungsten, a strong and quite dense material with a high melting temperature used for electric filaments and armor-piercing ammunition, as well as hard tungsten carbide machine tools. In World War II, wolframite mines were a strategic asset, due to its use in munitions and tools.

Wolframite is considered to be a conflict mineral due to the unethical mining practices observed in the Democratic Republic of the Congo.


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Name of Wolframite

The name "wolframite" is derived from German "wolf rahm" ("wolf cream"), the name given to tungsten by Johan Gottschalk Wallerius in 1747. This, in turn, derives from "Lupi spuma", the name Georg Agricola used for the element in 1546, which translates into English as "wolf's froth" or "cream" (the etymology is not entirely certain), and is a reference to the large amounts of tin consumed by the mineral during its extraction. Wolfram is the basis for the chemical symbol W for tungsten as a chemical element.

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2013年8月15日星期四

Wolframite

Wolframite, (Fe,Mn)WO4, is an iron manganese tungstate mineral that is the intermediate between ferberite (Fe2+ rich) and huebernite (Mn2+ rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite.
This mineral was historically found in Europe in Bohemia, Saxony, and Cornwall. China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Portugal, Russia, Australia, Thailand, South Korea, Rwanda, Bolivia, the United States, and the Democratic Republic of the Congo.
The name "wolframite" is derived from German "wolf rahm" ("wolf cream"), the name given to tungsten by Johan Gottschalk Wallerius in 1747. This, in turn, derives from "Lupi spuma", the name Georg Agricola used for the element in 1546, which translates into English as "wolf's froth" or "cream" (the etymology is not entirely certain), and is a reference to the large amounts of tin consumed by the mineral during its extraction.[5] Wolfram is the basis for the chemical symbol W for tungsten as a chemical element.
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Cantung Mine

The CanTung Mine is a primary producer of tungsten concentrates from underground operations.

Currently, the major features and facilities associated with Cantung are as follows:
  • The Cantung deposits, consisting of the Open Pit resource near surface, and the E Zone, underground.
  • The physical plant site including an underground mine, a small open pit, process plant, diesel power plant, workshops, warehouses, administration buildings, a town site and single status accommodation, and an airstrip.
  • Waste rock storage facilities and a tailings storage facility.
LOCATION

The Cantung Mine is located in the Nahanni area of western Northwest Territories, Canada, approximately 300 km by road northeast of Watson Lake, Yukon, close to the Yukon border. The mine is a primary producer of tungsten concentrate from open pit and underground mines. It was opened in 1962.

HISTORY

Prospectors discovered the Cantung Mine tungsten deposit in 1954, while looking for copper. In 1959, the Canada Tungsten Mining Corporation Ltd. was formed to acquire and develop the property. The Cantung Mine commenced production in 1962 from an open pit at the rate of 300 tons per day (stpd), with suspensions in 1963 due to low tungsten prices and in 1966 due to the destruction of the mill by fire. The construction of a new 350 stpd mill was completed in 1967 and, in 1969, the capacity was increased to 450 stpd.

In 1971, drilling discovered the "E Zone". This zone was accessed through an adit collared at the valley bottom, close to the town site. The mill began to process the underground ore in 1974. In 1975, the mill was further expanded to 500 stpd. A major mill expansion in 1979 increased the mill capacity to 1,000 stpd.

In 1985, Amax Inc consolidated ownership of the Cantung Mine and transferred all tungsten assets, including the Mactung Project at Macmillan Pass, to Canada Tungsten Mining Corporation, retaining majority control. Aur Resources Inc. (Aur) purchased Amax Inc's controlling interest in 1995 and Canada Tungsten and Aur merged in 1996.

In 1997, North American Tungsten Corporation Ltd. ("NATCL") purchased the Cantung mine, together with the related tungsten assets of the former Canada Tungsten Inc., from Aur.

After an improvement in tungsten prices commencing in 2000, NATCL reopened the Cantung mine in December 2001. Underground production and milling resumed at this time. In December 2003, NATCL was placed under the protection of the Companies Creditors Arrangement Act (CCAA), and the mine was closed. In November 2004, NATCL successfully completed a plan of arrangement to deal with creditors, allowing planning for reopening to commence. Preparatory work for the reopening began in July 2005, and production resumed in late September 2005.

The Cantung mine suspended operations in October 2009 and resumed production in October 2010.

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Tungsten Mining & Beneficiation

Tungsten is usually mined underground.  Scheelite and/or wolframite are frequently located in narrow veins which are slightly inclined and often widen with the depth. Open pit mines exist but are rare.
Tungsten mines are relatively small and rarely produce more than 2000t of ore per day.  Mining methods for tungsten ore are not at all exceptional and usually are adapted to the geology of the ore deposit.
Most tungsten ores contain less than 1.5% WO3 and frequently only a few tenths of a percent. On the other hand, ore concentrates traded internationally require 65-75% WO3.  Therefore, a very high amount of gangue material must be separated.  This is why ore dressing plants are always located in close proximity to the mine to save transportation costs.
The ore is first crushed and milled to liberate the tungsten mineral crystals.  Scheelite ore can be concentrated by gravimetric methods, often combined with froth flotation, whilst wolframite ore can be concentrated by gravity (spirals, cones, tables), sometimes in combination with magnetic separation. 


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Massive tungsten mine closer for Stanley

The village of Stanley, N.B., is one step closer to getting a massive tungsten mine.
Vancouver-based Northcliff Resources submitted its environmental-impact assessment to the federal government. It wants to start an open-pit tungsten mine in Stanley. The mine could employ hundreds of residents.
Northcliff’s Greg Davidson said the company has done the ground work and the public has nothing to fear.
“I certainly identify the concerns we’ve heard over the past couple of years. We’ve implemented mitigation strategies to minimize any impacts,” he said.
Northcliff expects to create 500 jobs during the construction phase — that's more than the population of Stanley.
It anticipates 300 jobs during the 27-year operation.


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2013年8月11日星期日

Ammonium Paratungstate Structure

In more recent literature (post WWII period), the anion in (NH4)10(W12O41)·5H2O has been shown to be [H2W12O42]10, containing two hydrogen atoms, keeping two hydrogen atoms inside the cage. The tungsten-oxygen cage, that is the heart of the anion requires 42 oxygen molecules. The correct formula notation for ammonium paratungstate is therefore (NH4)10[H2W12O42]·4H2O. The [H2W12O42]10 ion is known as the paratungstate B ion, as opposed to the paratungstate A ion, that has the formula [W7O24]6, similar to the paramolybdate ion. The existence of the paratungstate A ion, could not be confirmed by NMR spectroscopy, however.
Before about 1930, there has been some dispute about the exact composition of the salt, and both (NH4)10W12O41 and (NH4)6W7O24 were proposed. O.W. Gibbs remarked about this:
"The alkali tungstates are numerous and unusually complex. Salts of essentially different formul;ae approach so closely in percentage composition, that the differences lie very near the unavoidable errors of analyses. The analyses are hardly sufficiently close to decide the question upon purely analytical grounds."
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Ammonium Paratungstate Process

APT is produced by separating tungsten from its ore. Once the ammonium paratungstate is prepared, it is heated to its decomposition temperature, 600 °C. Left over is WO3, tungsten oxide. At that point, the oxide is heated in an atmosphere of hydrogen, reducing the tungsten to powder, leaving behind water vapor. From there, the tungsten metal powder can be fused into any number of things, from wire to bars to other shapes.


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2013年8月7日星期三

Tungsten Related Oxide could drived from APT



Intermediates, such as tungsten trioxide, tungsten blue oxide, tungstic acid, and ammonium metatungstate can be derived from APT as shown beyong, either by partial or complete thermal decomposition or by chemical attack.


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2013年8月6日星期二

Adjusting the balance of bullets - 02

By placing a plastic ball into the jacket, compressing it, and then placing a small quantity of
tungsten powder in the jacket followed by a final plastic ball, the weight can be increased and the
balance shifted, so that a combination of material quantities and positions can be developed that will
deliver good stability with any of the weights. Moving the weight toward the tip tends to make the
bullet more stable, but a point will be reached where the bullet does not turn to follow the trajectory
arc. At that point, the bullet is “over-stable” in the sense that rifling no long is required to keep it
pointed nose first, but instead the mass forward of the center of form will do this. If the trajectory is
very flat, or the range is quite short, the bullet will appear to be accurate.
But if the trajectory or range is normal for a rifle or long-range handgun, the bullet will be
pointed in the same direction as it was when it emerged from the barrel all the way to the target. That
is, it refuses to turn because it is so stable. In this case, the bullet presents an angle to the direction of
flight and thus offers a very low ballistic coefficient, compared to the same bullet with the center of
gravity shifted slightly further toward the rear. Extreme examples have resulted in the bullet dropping
sideways through the target (and the normal wind and air currents cause it to drift in an extreme
pattern from shot to shot, which appears to make the bullet seem inaccurate—and in practical terms,
it is).
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2013年8月5日星期一

Adjusting the balance of bullets - 01


The center of form of a bullet is generally defined as the point at which all of the axial forces could mathematically be concentrated from their actual vectors. The center of gravity of the bullet is the point where the bullet could be balanced against gravity. Although the actual center of gravity and center of form are located inside the bullet, we can simulate the location of the center of gravity by attempting to balance the bullet on a razor blade. The point along the side of the bullet where it most nearly will balance is close, in practical terms, to the actual center of gravity.

The center of form is harder to ascertain by external testing, because it is a measure of the forces working upon the bullet as it flies through the air. However, we can shift the center of gravity within the airframe of a given bullet by using a combination of two different densities of material in the core, each in its own separate “compartment”, so that the ratio of length of each will determine where the center of gravity lies.

For instance, linear polyethylene balls are available in various diameters that will slip easily into nearly any caliber of bullet jacket. These polymer balls will compress under swaging pressure to fill the space available, yet add only a few grains to the total bullet weight. Filling the entire bullet with two or more plastic balls creates a standard length of bullet that has only a few more grains than the jacket itself. A typical example would be a 58 grain .308 rifle bullet, which is normal length for a 168 grain bullet. Another would be a 40 grain 9mm which has the appearance of a normal 140 grain bullet.

These light bullets can be fired at extremely fast speeds with the correct charge of fast burning powder, but they generally are not accurate.


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Short lengths with normal weight bullets

Using a dense material also means that the length of a normal weight bullet can be shortened, for such purposes as gaining additional powder capacity in the case, fitting into a short throated barrel without impacting against the rifling, or allowing the innovative use of longer wildcat cases (such as arimmed .30 rifle case cut back to make an extra long .44 handgun case, which could fit a .44 Magnum revolver cylinder). In some situations where the limit of bullet length is all that prevents an innovative idea from working, using a normal weight with a tungsten core can reduce bullet length, and thus reduce the overall cartridge length enough to try a new concept.

The amount of reduction in length is approximately 60 percent of the original lead core bullet length, when filled with tungsten powder. This will vary with the ratio of jacket to core weight, of course, but it is normally safe to assume that a minimum of 25% shorter length will result in the same weight of bullet, when changing from a lead core to a tungsten core. A simple example is the use of a slower burning, bulkier powder behind a normal weight .380 or .25 ACP bullet when used in a pisto that has been equipped with a longer than usual barrel. The shorter bullet allows more powder room in the cartridge, which can then be used to develop safe loads that deliver a longer burn curve to accelerate the bullet through a longer barrel than would normally be used in that caliber.


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2013年8月1日星期四

Heavy weights in standard length bullets

The most obvious use of tungsten powder in bullet design is to make heavy bullets that will fit into normal length chambers, feed through standard length actions and fit into normal magazines and revolver cylinders.

Because the bullet density is increased, and its length remains the same, the spin rate required to stabilize it does not change appreciably. This means a second benefit is that the normal twist rate of barrel should stabilize the heavy tungsten core bullet, whereas it would not stabilize a lead core bullet of the same weight (since the spin rate required increases with bullet length, and only incidently with the bullet weight because normally the density of material is not changed).

In addition to the savings in not having to purchase special barrels to fire these heavy bullets accurately, the normal length tungsten core bullets have the additional benefit of not wasting additional energy in spinning faster, and because they do not have to spin faster, they also have less problem with radial imbalances than a conventional heavy weight lead core bullet. It is well known that the faster a bullet is spun about its axis, the more centrifugal force is generated by slight imbalances in the jacket wall thickness, tiny voids or other anomolies of construction. If all else were equal,the bullet which can be stablilized with the lowest twist rate will tend to be more accurate, and this would be the tungsten core bullet. Typical uses might be 80-100 grain .224 bullets, 130-145 grain .243 bullets, and 200-250 grain .308 bullets for long range, high delivered energy hunting loads or stable target rounds, or extra-heavy handgun bullets that will not protrude either into the case or project beyond the standard cartridge length


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Use of Tungsten in Bullet Design - 01

Tungsten as a solid material is difficult and expensive to machine because of its extreme hardness, but as a powder, it can be compacted into a bullet jacket at normal swaging pressures used for lead core bullets. With the proper grade and quality of particle size control, tungsten powder is relatively easy to handle and compacts to nearly the same density as solid metal.

Tungsten is approximately 1.7 times heavier than lead. A tungsten core bullet having the same length, caliber and shape as another bullet with a lead core would weigh more. The exact amount could be calculated by first weighing the bullet jacket, then subtracting this from the total bullet weight, and multiplying the resultant lead core weight by 1.7, and finally adding back the jacket weight. For instance, a 168 grain .30 caliber match bullet with a lead core typically would have a 50 grain jacket and a 118 grain lead core. An identical appearing tungsten core bullet would weigh 250.6 grains


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