2013年9月25日星期三

Lithium Tungstate Uses

Lithium tungstate is used to produce high density water solutions. Like other high density fluids, it is often used in the separation of minerals and other solids.

This use was developed in the early 1990s to address issues with existing high density fluids such as toxicity, safety, and stability, Unlike methylene iodide and bromoform it can safely be used in an indoor environment without a fume hood with only ordinary common sense safety precautions such as protective gloves and safety glasses.

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Lithium Tungstate Structure

The salt consists of tetrahedrally coordinated Li and W centres bridged by oxides. The W-O and Li-O bond distances are 1.79 and 1.96 Å, respectively. These differing bond lengths reflect the multiple bond character of the W-O interaction and the weaker ionic bonding between the Li-O interactions. The solid undergoes phase transitions at high pressures, such that the coordination geometry at tungsten becomes octahedral (six W-O bonds). For example at 40 kilobars, it adopts a structure related to wolframite.

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Lithium Tungstate Definition from Wiki

Lithium tungstate is the inorganic compound with the formula Li2WO4. It is a white solid that is soluble in water. The compound is one of the several orthotungstates, compounds that feature the tetrahedral WO42- anion.


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2013年9月22日星期日

Cesium Tungstate--about Cesium

Cesium or Caesium (atomic symbol: Ce, atomic number: 55) is a Block S, Group 1, Period 6 element with an atomic weight of 132.9054519. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe] 6s1. Cesium Bohr ModelThe cesium atom has a radius of 265 pm and a Van der Waals radius of 343 pm. Cesium is a member of the alkali group of metals. It is one of three metals that occur as a liquid at room temperature, the others being mercury and gallium. Cesium's main commercial source is pollucite ore; however, it is also found in beryl, avogadrite, pezzottaite, and londonite. Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860 and first isolated by Carl Setterberg in 1882. In its elemental form, cesium has a silvery gold appearance. The word Cesium originates from the Latin word "caesisus," meaning "sky blue," which refers to the vibrant blue lines in its spectrum.

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Cesium Tungstate--data

Cesium Tungstate

Cs2WO4

CAS 13587-19-4

Product Product Code Order or Specifications
(2N) 99% Cesium Tungstate CS-WO-02 Contact American Elements
(3N) 99.9% Cesium Tungstate CS-WO-03 Contact American Elements
(4N) 99.99% Cesium Tungstate CS-WO-04 Contact American Elements
(5N) 99.999% Cesium Tungstate CS-WO-05 Contact American Elements

PROPERTIES
Compound Formula
Mol. Wt.
Appearance
Density
Exact Mass
Monoisotopic Mass
MSDS
Cs2O4W
513.65
Solid
N/A
513.741485
513.741485
Safety Data Sheet
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Cesium Tungstate

Cesium Tungstate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

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2013年9月21日星期六

References of Tungstate

Solutions of tungstates, like those of molybdates, give intensely blue solutions of complex tungstate(V,VI) analoguous to the molybdenum blues when reduced by most organic materials.

Unlike chromate, tungstate is not a good oxidizer, but like chromate, solutions of tungstate condense to give the isopolytungstates upon acidification.

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