Zirconium Tungstate Definition by Wiki

At high pressure, zirconium tungstate undergoes a series of phase transitions, first to an amorphous phase, and then to a U3O8-type phase, in which the zirconium and tungsten atoms are disordered.

Zirconium tungstate (Zr(WO4)2) is a metal oxide with unusual properties. The phase formed at ambient pressure by reaction of ZrO2and WO3 is a metastable cubic phase, which has negative thermal expansion characteristics, namely it shrinks over a wide range of temperatures when heated. In contrast to most other ceramics exhibiting negative CTE (coefficient of thermal expansion), the CTE of ZrW2O8 is isotropic and has a large negative magnitude (average CTE of -7.2x10−6K−1) over a wide range of temperature (-273 °C to 777 °C). A number of other phases are formed at high pressures.

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