显示标签为“calcium tungstate”的博文。显示所有博文
显示标签为“calcium tungstate”的博文。显示所有博文

2015年11月23日星期一

Calcium Tungstate Crystals Aim to Light up Dark Matter

German scientists hunting dark matter are set to produce half a tonne of high-purity calcium tungstate for their detectors, one 1kg crystal at a time. The CRESST-II experiment based in Gran Sasso, Italy is currently seeking this enigmatic substance, thought to explain the universes structure, with 10kg of calcium tungstate (CaWO4). Now Andreas Erb and Jean-Côme Lanfranchi are preparing crystals for its larger successor EURECA, which will begin operation in the French Alps in 510 years.

Gravitational effects suggest as-yet-unobserved dark matter in the universe outnumbers more familiar atomic matter four to one. Erb, Lanfranchi and their colleagues are hunting leading theoretical candidates, Weakly Interacting Massive Particles (WIMPs). That name reflects their size – up to a lead atom’s mass – and the limited interaction with atomic matter that makes them hard to find, or ‘dark’. ‘They have to interact weakly to agree with the matter needed,’ says Richard Gaitskell from Brown University in the US, who isn’t involved in the calcium tungstate experiments.


Erb explains that the detectors should be able to pick up dark matter particles when they hit atomic nuclei in the crystals. ‘A higher sample mass gives a higher probability of such events.’ But distinguishing the miniscule amount of heat WIMP–nucleus collisions would produce requires detectors cooled to 10mK and shielded from ambient radioactivity.

CRESST/EURECA is the only team hunting dark matter with calcium tungstate, which has two advantages. Firstly, its different atoms cover a range of possible WIMP masses. ‘No matter the mass, you always have a nucleus with a high probability of interacting,’ Erb says. Second, it would also emit light when a WIMP hits it and monitoring the different signals will help the scientists eliminate background noise. 

Having initially purchased crystals, this need for extreme sensitivity drove Erb and Lanfranchi to produce their own. ‘They weren’t pure enough for the background we want,’ Erb recalls. To avoid oxidation at calcium tungstate’s 1600°C melting temperature, the crucibles are made from rhodium, with their 12cm diameter vessel costing €120,000 (£97,300). Erb says that if they can grow two or three 1kg crystals per week then they will have the required amount for EURECA in about five years.

2015年8月27日星期四

Calcium Tungstate Applications

Calcium tungstate is a very important chemical materials, which has applications in mainly ways:
1. For production of ammonium paratungstate, tungsten trioxide, tungsten iron, steel, carbide, tungsten materials, tungsten and tungsten alloys and other tungsten products;
2. Used as raw materials of tungsten series chemical products;
3. For fluorescent paint, photography screen pipe, medicine, X-ray photograph and fluorescent lighting;
4. Calcium tungstate is also used for luminous paint, fluorescent lights, neon lights, X-rays screen, medicine, scintillation counter and lasers.






Calcium Tungstate Advantages

The interest in CaWO4 and CaMoO4 has been driven by the fact that these compounds have especially attractive properties for a variety of optical applications (phosphors, laser hosts, scintillators).
Recently, CaWO4 was implemented in the CRESST dark matter search, enabling discrimination between electron and nuclei recoils. Different types of interaction events can be identified by simultaneously measuring a combination of phonon and scintillation signals from cryogenic phonon-scintillation detectors (CPSD) operating at milli-kelvin temperatures. This technique offers high sensitivity and the unique advantage of background identification, which is crucially important for experimental searches for rare events.



Calcium Tungstate Manufacturing Process

The following methods is for calcium tungstate manufacturing process:
1.Mix sodium tungstate and sodium sulfide and dissolve into water, then add zinc chloride aqueous solution. After filtration, treat filtrate with calcium chloride, and then we can get calcium tungstate.
2.Calcium oxide/calcium hydroxide reacts with tungsten oxide/tungsten tetrahydroxide in alkali hydroxide/carbonate solution, and then calcium tungstate is obtained.
3.Burning tungsten trioxide and calcium carbonate in 1070℃ or treatment between sodium tungstate solution and calcium chloride solution or processing scheelite.


Calcium Tungstate

Calcium tungstate is white powder with tetragonal structure. Its relative density is 6.062. Slightly soluble in water and ammonium chloride solution. Dissociation in hydrochloric. Calcium tungstate is a very important chemical materials, mainly used for production of ammonium paratungstate, tungsten trioxide, tungsten iron, steel, carbide, tungsten materials, tungsten and tungsten alloys and other tungsten products.
Calcium Tungstate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.